화학공학소재연구정보센터
학회 한국고분자학회
학술대회 2008년 봄 (04/10 ~ 04/11, 컨벤션 뷰로(대전))
권호 33권 1호
발표분야 기능성 고분자
제목 Preparation of Nanoporous Aliphatic Polyimides
초록 Triblock copolyimides having thermally labile block were prepared to introduce nanopores into the aliphatic polyimides. A thermally labile polymer, poly(propylene glycol), was modified to obtain PPG having amino end group. PPG was incorporated into aliphatic polyimides, affording triblock copolymers containing PPG block. The thermal properties the copolymers were investigated by thermogravimetric analysis and differential scanning calorimetry. Thermal decomposition of PPG block in the copolymers was carried out at 240℃ under various pressure conditions to obtain porous polyimide films. The pore characteristics, optical absorption, and dielectric constants of the polyimides were investigated.
저자 이창형1, 조성열1, 김중곤2, Kazuaki Kudo3, 정찬문1
소속 1연세대, 2Hanwha Chemical R&D Center, 3the Univ. of Tokyo
키워드 polyimide; dielectric constants
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