화학공학소재연구정보센터
학회 한국화학공학회
학술대회 2020년 가을 (10/14 ~ 10/16, e-컨퍼런스)
권호 26권 1호, p.16
발표분야 고분자
제목 C70-based Water/Ethanol-Soluble Fullerene Acceptor for Solvent Composition-Tolerant Performance of Eco-Friendly Polymer Solar Cells
초록 Eco-friendly polymer solar cells (eco-PSCs) based on aqueous-soluble conjugated materials have received great attention. In this work, the development of a C70-based fullerene (PC71BO15) for eco-PSCs processed by water/ethanol is reported. The PCEs of fabricated eco-PSCs up to 2.51%, which is the highest value for aqueous-processed PSCs, was achieved thanks to the promising aggregation behavior and enhanced light absorption ability. The optimized PCE of the PC71BO15-based eco-PSCs is 73% higher than that of the PC61BO15-based. Also, the PC71BO15-based eco-PSCs show much greater tolerance in their PCEs to the water/ethanol composition. PC71BO15-based eco-PSCs at a 30:70 water/ethanol ratio maintain 89% of the optimal performance, whereas only 45% for PC61BO15-based devices. Different aggregation behaviors induced large difference in terms of water-tolerant behavior, which is explored by several characterizations. The PC71BO15-based eco-PSCs with aqueous processing can ensure excellent reproducibility.
저자 김창균1, 강현범1, 최나연1, 이승진1, 김영권1, 김진우1, 우즈앙2, 우한영2, 김범준1
소속 1한국과학기술원, 2고려대
키워드 고분자
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