화학공학소재연구정보센터
학회 한국고분자학회
학술대회 2014년 봄 (04/10 ~ 04/11, 대전 컨벤션센터)
권호 39권 1호
발표분야 분자전자 부문위원회
제목 Enhacement of Efficiency and Air stability in Polymer Solar Cell with modified PEDOT/PSS buffer layer using Polymeric additives
초록 In most of the bulk heterojunction (BHJ) OSCs, poly(4-styrene sulfonate)-doped poly(3,4-ethylenedioxythiophene (PEDOT:PSS) is widely used as hole transport layers (HTL). However, PEDOT:PSS accelerates the degradation of OSCs due to its highly hygroscopic and acidic nature. To solve this problem, PEDOT/PSS was modified to have a resistance from water using polymeric additive. As a results, power conversion efficiency(PCE) increased from 2.51% to 3.30% by 31% and half-life times also increased around 3 times. The electrical and morphological properties of modified PEDOT/PSS was analyzed by X-ray photoelectron spectroscopy(XPS), Kelvin probe, 4-point probe meter and atomic force microscopy(AFM) respectively. This method is very simple on the production process and shows a lot of applicability in various organic electric device such as OPV, OLED, OTFT etc..
저자 이정준1, 김중현1, 이승환1, 박홍관1, 조원석1, 이선종2
소속 1연세대, 2미시간 대
키워드 Organic photovoltaic (OPV); PEDOT/PSS; Polymeric additive; Work function; Air stability
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