| 학회 |
한국고분자학회 |
| 학술대회 |
2017년 가을 (10/11 ~ 10/13, 제주컨벤션센터) |
| 권호 |
42권 2호 |
| 발표분야 |
분자전자 부문위원회 I |
| 제목 |
Inter-Ligand Energy Transfer in Heteroleptic Ir complexes: Comprehensive investigations of its fast dynamics and mechanism |
| 초록 |
The heteroleptic Ir(III) complexes containing of two dfppy ligands and an ancillary ligand (dpq or tpphz) was synthesized to obtain evidence of the ILET process that can be observed in the presence of energetically different ligands in metal complexes. From the temperature dependency results, we found that the rigidity of the environment is a very important factor affecting the ILET process. Indeed, the ILET appears to require some structural distortion because this transition is forbidden when the ligands are arranged in an orthogonal geometry. Complex 1 bearing the tpphz ancillary ligand showed slower ILET dynamics than complex 2 with the dpp ligand. Both of 1 and 2 constitute good models for understanding the ILET dynamics based on TA spectroscopy with excitation with different wavelengths. |
| 저자 |
박재현, 김종훈, 김태현, 강상욱, 손호진
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| 소속 |
고려대 |
| 키워드 |
Inter-Ligand Energy Transfer in Heteroleptic Ir complexes: Comprehensive investigations of its fast dynamics and mechanism |
| E-Mail |
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