화학공학소재연구정보센터
학회 한국공업화학회
학술대회 2018년 가을 (10/31 ~ 11/02, 제주국제컨벤션센터(ICC JEJU))
권호 22권 2호
발표분야 에너지저장.변환_포스터
제목 Correlation of Molecular Weight and Orientation Properties Among Quinacridone and Acceptor Units for Organic Photovoltaics.
초록 Polymer-based organic solar cells (PSCs) have attracted a great deal of interest as a promising energy resource because of their advantages such as low manufacturing cost and flexible device applications over inorganic solar cell.  
Donor- π -acceptor (D-π-A) type copolymers were synthesized containing quinacridone as donor and introducing thienothiophene as π-bridge through Suzuki coupling reaction. Depending on benzothiadiazole and quinoxaline derivertives introduced as acceptors.  
π–spacer has recently gained attention due to its property enhancement in D-π–A type conjugated copolymers. In this respect, the introduction of π–spacer have mainly shown the follwing results: 1) Changes in optical and electrochemical properties  2) good charge transfer property  3) close packing of polymers by improvement intermolecular π-π interaction. The photo-physical, electrochemical and photovoltaic properties of the new polymers have been studied and compared.
저자 김두헌1, 한용운2, 문두경2
소속 1한국과학기술(연), 2건국대
키워드 Organic Photovoltaic; Quinacridone (Qc); π–spacer; molecular weight
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