| 학회 |
한국고분자학회 |
| 학술대회 |
2014년 가을 (10/06 ~ 10/08, 제주 ICC) |
| 권호 |
39권 2호 |
| 발표분야 |
분자전자 부문위원회 |
| 제목 |
Novel π-Spacer Linked Bis-Benzothiadiazole Blocks for Dominant Polarity Tuner in Organic Field-Effect Transistors |
| 초록 |
In general, steric hindrance of the polymer chains results in poor electrical performance in the semiconducting polymer-based organic field-effect transistors (OFETs). Recognizing the importance of the molecular co-planarity and with the aim of developing new, ideal strong acceptor building units in semiconducting polymers for high-performance organic electronics, herein we present a facile single-step synthesis of novel π-spacer linked monomers with enlarged planarity relative to a conventionally used acceptor, benzothiadiazole (BT). The novel π-spacer linked bis-benzothiadiazole units have been incorporated into centro-symmetric ketopyrrole cores to facilitate charge transport by enhancing the planarity of the polymer backbones with strong accepting properties. These polymers yield relatively well-balanced ambipolar OFET performances with tunability in the dominant polarity. |
| 저자 |
한아름1, 김종기2, 홍자연2, 김경식1, 이정훈2, 신태주2, 양창덕1, 오준학2
|
| 소속 |
1포항공과대, 2울산과학기술대 |
| 키워드 |
ambipolar semiconductors; bis-benzothiadiazole; centro-symmetric ketopyrrole; organic field-effect transistors (OFETs); unsaturated linkers
|
| E-Mail |
|
