화학공학소재연구정보센터
학회 한국고분자학회
학술대회 2014년 가을 (10/06 ~ 10/08, 제주 ICC)
권호 39권 2호
발표분야 고분자가공/복합재료-자가치유 고분자와 복합소재
제목 Synthesis and Characterization of Polyhedral Oligomeric Silsesquioxane(POSS) Coating Polyethylene Glycol Units.
초록 The octakis(3-chloropropyl)silsesquioxane(POSS-Cl) have rigid silica core surrounded by symmetrically distributed functional groups. POSS-Cl were good candidate for considerable chemical stability and specific physical properties. Methoxy polyethylene glycol 350 (MePEG350)-based electrolyte have been popular for lithium ion polymer electrolyte application. Polymer electrolyte have good candidate for ion conductivity, chemical stability and mechanical strength. POSS coating polyethylene glycol units (POSS/MePEG350) was synthesized by the reaction of POSS-Cl and MePEG350 using NaH in THF solution. POSS/MePEG350 can be expected to have high mechanical and thermal properties As well as good conducting for Lithium batteries because of POSS modification. The characteristics of POSS/MePEG350 were characterized by TGA, DSC, FT-IR, and 1H-NMR.
저자 김성관, 임정혁, 김경민
소속 한국교통대
키워드 POSS; hybrid nanomaterial; polymer electrolyte
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