화학공학소재연구정보센터
학회 한국공업화학회
학술대회 2013년 가을 (10/30 ~ 11/01, 대전컨벤션센터)
권호 17권 2호
발표분야 제지산업 경쟁력 제고를 위한 친환경 기술의 최신동향
제목 Properties of Cellulose Nanocrystal/Polyvinyl Alcohol-Based Nanocomposites
초록 The characteristics of two types of cellulose nanocrystals (CNCs), i.e., cellulose nanowhiskers (CNWs) and cellulose nanofibrils (CNFs) and their reinforcement of polyvinyl alcohol (PVA)-based nanocomposites are described. CNWs were isolated by sulfuric acid hydrolysis while CNFs were isolated by 2,2,6,6-tetramethylpiperidine-1-oxyl radical (TEMPO)-mediated oxidation. Based on measurements by transmission electron microscopy of individual CNWs were about 6.96±0.87 nm wide and 178±55 nm long, while CNFs were 7.07±0.99 nm wide. The incorporation of CNWs and CNFs into PVA matrix at 5% and 1% levels, respectively, resulted in maximum tensile strength, indicating their different reinforcement efficiencies. These results suggest a relationship between the reinforcing potential of CNCs and their physical characteristics.
저자 박병대1, Adya Singh1, Valerio Causin2, 이선영3
소속 1경북대, 2Department of Polymer Science, 3Univ. of Padova
키워드 cellulose nanowhiskers; cellulose nanofibril; polyvinyl alcohol; nanocomposites; mechanical properties
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