| 학회 |
한국고분자학회 |
| 학술대회 |
2014년 봄 (04/10 ~ 04/11, 대전 컨벤션센터) |
| 권호 |
39권 1호 |
| 발표분야 |
고분자구조 및 물성 |
| 제목 |
Improvement of Thermal and Mechanical Properties of Double Metal Cyanide Catalyzed Aliphatic Polycarbonates through Graft Copolymerization |
| 초록 |
The low cost and low toxicity of carbon dioxide (CO2) make it an attractive industrial chemical reagent, so methods for using CO2 as a practical carbon feedstock are being aggressively investigated. One of the most intensely studied processes involves the use of CO2 in the synthesis of polymers, especially polycarbonates. Terpolymerization of CO2 with alicyclic epoxides has been carried out by using double metal cyanide catalyst with excellent catalytic activity. In order to improve various properties of synthesized polycarbonates, we modified the pendant vinyl groups on polymer chain via thiol-ene click reaction and epoxidation/ring-opening reaction. We attached molecules whichs have multi-functional groups such as hydroxyl and amino groups. Mechanical and thermal properties of the resultant polycarbonates were characterized by gel permeation chromatography, universal testing machine, thermogravimetric analysis, differential scanning calorimetry and various spectroscopic techniques. |
| 저자 |
변성진1, 김강률1, 윤성환1, 김우섭2, 김응수2, 신진복2, 김일1
|
| 소속 |
1부산대, 2삼성전기 |
| 키워드 |
Carbon dioxide; Epoxides; Double metal cyanide catalyst; Terpolymerization
|
| E-Mail |
|
