화학공학소재연구정보센터
학회 한국고분자학회
학술대회 2004년 봄 (04/09 ~ 04/10, 고려대학교)
권호 29권 1호, p.352
발표분야 분자전자 부문위원회
제목 Effect of Molecular Weight on ionic conductivities of Chemical Gel Polymer Electrolyte Based on (PEO)n(MA)y
초록 In this work, a series of gel type polymer electrolytes based on (PEO)n(MA)y has been prepared and the effects of their molecular structures on ionic conductivities of the obtained gel electrolytes were investigated. Liquid electrolyte composed of EC : EMC : PC : DEC (20 : 60 :10: 10) was mixed with a small amount of gel forming monomer, (PEO)n(MA)y. Final electrolyte formulation consisted of 1.15M LiPF6 in EC : EMC : PC : DEC (20 : 60 :10: 10). Lauryl peroxide was used as a thermal initiator. Electrolyte was then polymerized by a thermal reaction at 80 oC for 90 min.
Gel was attainable well as PEO chain length was short. but ionic conductivities was high when PEO chain length was long.
저자 김진환, 윤수진
소속 성균관대
키워드 Gel Polymer Electrolytes(GPEs); (PEO)n(MA)y PEO chain length; ionic conductivity
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