화학공학소재연구정보센터
학회 한국고분자학회
학술대회 2012년 봄 (04/12 ~ 04/13, 대전컨벤션센터)
권호 37권 1호
발표분야 기능성 고분자
제목 Photo-Cleavable Cross-Linked Nanoporous Templates via Dual Responsive Photoresists and Silicon-Containing Block Copolymers
초록 A simple and novel method was developed to fabricate a photo-cleavable cross-linked nanoporous template for freestanding one-dimensional (1D) nanostructure arrays based on self-assembly of silicon-containing block copolymers and a lithographic bilayer system. Removal of the cross-linked bottom layer after fabrication is not easy. Therefore, we propose a dual responsive bottom layer into which the nanopatterns of block copolymer are transferred by oxygen reactive ion etching. Because the dual responsive layer becomes cross-linked by heating, it can be used as a hard template during the etching process. It becomes soluble again by chain scission upon exposure to light. Therefore, it can be easily removed by the lift-off process. These versatile templates of nanoporous structures can be applied to create freestanding 1D nanostructures of a variety of functional materials.
저자 박창홍, 구세진, 조경천, 정경옥, 김진백
소속 한국과학기술원
키워드 self-assembly; nanoporous template; photoresist; block copolymer
E-Mail