화학공학소재연구정보센터
학회 한국고분자학회
학술대회 2010년 가을 (10/07 ~ 10/08, 대구 EXCO)
권호 35권 2호
발표분야 분자전자소재 및 소자
제목 Synthesis and Characterization of Carbazole-based Bipolar Type Organic Dyes for Dye-Sensitized Solar Cells
초록 Carbazole moiety have been used as a active layer in fields of organic light-emitting diodes by virtue of excellent hole-transporting ability. carbazole unit also have a strong electron donating ability which lead to red shift of absorption spectrum. we synthesized organic dye sensitizers based on Carbazole moiety as a donor. We also prepared a series of organic dyes with thiophene units and 3,4-ethylenedioxythiophene (EDOT) as a π-conjugation linkage, for dye sensitized solar cells. Cyano acetic aicd was employed as a acceptor for all organic dyes. To introduce EDOT moiey as a spacer increase absorption wavelength, because of their electron-rich character. The structures of a series of dyes were established using FT-IR spectroscopy and H-NMR. The electrochemical properties of the dyes were determined from the cyclicvoltammetry and absorption spectroscopy. The photovoltaic of synthesized organic dye will be discussed.
저자 임민정1, 진성호1, 윤회원1, 김애진1, 김열호1, 이재욱2, 제갈영순3
소속 1부산대, 2동아대, 3경일대
키워드 DSSCs; Carbazole derivatives
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