| 학회 |
한국고분자학회 |
| 학술대회 |
2007년 가을 (10/11 ~ 10/12, 일산킨텍스) |
| 권호 |
32권 2호 |
| 발표분야 |
분자전자 소재 및 소자 기술(분자전자 부문위원회) |
| 제목 |
High Quality Organic Single Crystalline Thin Films for Nonlinear Optical Applications |
| 초록 |
New series of nonlinear optical crystals based on configurationally locked polyene (CLP) are developed and the growth of single crystalline thin films by melt-based techniques is demonstrated. The chromophores consist of -conjugated hexatriene bridge between dialkylamino or methoxy electron donors and dicyanomethylidene electron acceptor. The physical and nonlinear optical properties, and the single crystal X-ray structures of these chromophores are characterized. The chromophore DAT2 exhibits a noncentrosymmetric crystalline arrangement (monoclinic, P21) and shows a large macroscopic nonlinearity. We demonstrate the growth of single crystals of DAT2 by a Bridgman-type melt growth technique and vapor growth technique. The grown single crystalline DAT2 films exhibit good optical quality and suitable size for fabrication of photonic devices. We also investigated crystal engineering of CLP crystals by co-crystallization and tailor-made auxiliaries. |
| 저자 |
O-Pil Kwon1, Seong-Ji Kwon2, Ashutosh Choubey3, Mojca Jazbinsek2, Peter Günter4
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| 소속 |
1Swiss Federal Institute of Technology / Department of Molecular Science and Technology, 2Ajou Univ., 3Department of Molecular Science and Technology, 4Swiss Federal Institute of Technology |
| 키워드 |
Organic Single Crystalline; Nonlinear Optical
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| E-Mail |
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