초록 |
We have synthesized triblock copolymers having self-complementary hydrogen bonding units using RAFT polymerization. These polymers showed an aggregation behavior by inter- and intramolecular interactions in chloroform or toluene, while it freely dissolved in THF. At low concentration, polymers formed nanoparticles, and the size increases with increasing polymer concentration. The polymers showed the both particle and network properties either. Detailed analysis results such as gel permeation chromatography, dynamic light scattering, viscosity, dye incorporation, and atomic force microscopy will be presented. |