화학공학소재연구정보센터
학회 한국공업화학회
학술대회 2021년 가을 (11/03 ~ 11/05, 대구 엑스코(EXCO))
권호 25권 2호
발표분야 포스터-도료·코팅
제목 Superhydrophobic coatings based on polyurethane acrylate/fluorinated hyperbranch amine/hydrophobic nano-silica hybrids
초록 Robust transparent mechanically durable superhydrophobic coatings are highly sought in day-to-day life as well as in industry over the years due to their various applications. In this study, superhydrophobic coatings were developed based on the hybrids consisting of polyurethane acrylates (PUA), fluorinated hyperbranched amines (F-HBA) and  a small amount of hydrophobically modified silica nanoparticles,  Structure and performance properties of the coating materials were characterized by FTIR, DMA, FESEM, AFM and WCA analysis.  It was demonstrated that the PUA and F-HBA can form a crosslinked network with low surface energy via the aza-Michael addtion reactions, and presence of the silica nanoparticles provide surface roughness.  The coatings showed a water contact angle as high as 150° along with fairly good optical transparency. It was also revealed that such superhydrophobicity was maintained after repeated mechanical abrasion using a sandpaper.
저자 허성민, 장영욱
소속 한양대
키워드 superhydrophobic coating; fluorinated HBP; nano-silica; durability
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