화학공학소재연구정보센터
학회 한국재료학회
학술대회 2012년 봄 (05/17 ~ 05/18, 무주덕유산리조트)
권호 18권 1호
발표분야 C. 에너지/환경 재료(Energy and Environmental Materials)
제목 A study on the improved microstructure and morphology of CuInS2 absorber layer for thin film solar cells
초록 CuInS2 (CIS) absorber thin films were prepared on soda lime glass substrates by sulfuriztion of sputtering deposited stacked Cu/In precursor thin films. The Cu-In precursor thin films were sulfurized in the mixture of H2S (5 %) + N2 (95 %) atmosphere with different post-annealing steps. The effect of different post-annealing steps such as holding times and increasing rates on the structural, compositional, chemical binding energy, optical and electrical properties of the CIS thin films were studied using FE-SEM (field-emission scanning electron microscopy), XRD (X-ray diffraction), EDS (energy dispersive spectroscopy), Raman spectroscopy, Hall measurement, respectively. The XRD, Raman, FE-SEM, Hall measurement and UV-vis results indicated that the properties of sulfurized CIS thin films were strongly related to the post-annealing steps. In particular, the microstructures of the sulfurized CIS thin films were denser without voids using post-annealing process as compared to that without post-annealing process. Further detailed analysis and discussion for effect of post-annealing steps on the properties CIS thin films will be discussed.
저자 Myeng Gil Gang1, Seung Wook Shin2, Jun Hee Han1, Jae Ho Yun3, Jong-HaMoon1, Jeong Yong Lee3, Jin Hyeok Kim4
소속 1Department of Materials Science and Engineering, 2Chonnam National Univ., 3KAIST, 4Photovoltaic Research Group
키워드 CuInS2 (CIS); sulfurization process; post-annealing; thin film solar cells; post-annealing process
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