| 학회 |
한국화학공학회 |
| 학술대회 |
2005년 가을 (10/21 ~ 10/22, 인하대학교) |
| 권호 |
11권 2호, p.2381 |
| 발표분야 |
열역학 |
| 제목 |
High-Pressure Phase Behavior of Carbon Dioxide in Ionic Liquid: 1-Alkyl-3-Methylimidazolium bis(Trifluoromethylsulfonyl)imide |
| 초록 |
In order to gain insight into the phase behavior of ionic liquids + supercritical fluids, the phase boundaries of a binary mixture of an ionic liquid and a supercritical fluid has been studied experimentally. High-pressure phase behavior of carbon dioxide in the ionic liquid 1-alkyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide ([Cn-mim][Tf2N]) are presented in a wide range of solution concentration at temperatures between 303 K to 343 K and at pressures up to 40 MPa. The equilibrium pressure at a given temperature and concentration were measured using a high-pressure apparatus equipped with a variable-volume cell. The equilibrium pressure increased very sharply with increasing concentration of CO2 in the ionic liquid-rich phase. The solubility of CO2 in the ionic liquid-rich phase decreased with an increase in temperature. |
| 저자 |
오세균, 이병철
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| 소속 |
한남대 |
| 키워드 |
ionic liquid; phase behavior; supercritical; solubility; carbon dioxide
|
| E-Mail |
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| 원문파일 |
초록 보기 |
