화학공학소재연구정보센터
학회 한국화학공학회
학술대회 2009년 봄 (04/23 ~ 04/24, 광주 김대중컨벤션센터)
권호 15권 1호, p.738
발표분야 열역학
제목 Phase equilibria for water + carbon dioxide + nitrogen in gas hydrates
초록 Phase equilibria involving gas hydrates and the effect of nitrogen on phase equilibria have been studied by several researchers. The studies on 4-phase equilibria with aqueous, liquid carbon dioxide, vapor, and hydrate are rare.
The new indirect method*1 used for measurement of solubility of carbon dioxide in water was used in present study. Predetermined composition of water, carbon dioxide, and nitrogen was injected to variable volume view cell in water bath. The temperature of system was measured for 4-phase equilibrium. The results were analyzed by CSMGem*2.
[1] Kim, Y. S., B. D. Lim, et al. (2008). "Solubilities of Carbon Dioxide, Methane, and Ethane in Sodium Chloride Solution Containing Gas Hydrate." J. Chem & Eng Data 53(6): 1351-4.
[2] Sloan, E. D. and C. A. Koh (2008). Clathrate hydrates of natural gases. Boca Raton, FL, CRC Press.
저자 김선형, 이재을, 서명도, 이철수, 강정원
소속 고려대
키워드 gas hydrate; phase equilibria
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