화학공학소재연구정보센터
학회 한국고분자학회
학술대회 2009년 가을 (10/08 ~ 10/09, 광주과학기술원 오룡관)
권호 34권 2호
발표분야 에너지변환 및 저장시스템(분자전자 부문위원회)
제목 A low band gap donor-acceptor conjugating new copolymers based on 2-pyran-4-ylidemalononitrile derivatives for organic solar cells
초록 Mixtures of conjugated polymers and fullerene derivative (PCBM) command considerable attention for application in organic solar cells. In order to improve their efficiency, the design of new materials that absorb at longer wavelengths (or low band gab) is of substantial interest. We synthesis and characterize new copolymers based on 2-pyran-4-ylidenemalononitrile and derivatives of dialkoxy-divinylbenzene and fluorene to get low band gap and high Voc. A series of copolymers with and 2-pyran-4-ylidene-malononitrile (PM) derivatives were synthesized successfully through the Heck coupling reaction and Suzuki coupling reaction. In this presentation, the optical, electrochemical, and photovoltaic properties of the blend of new copolymers and PCBM will be discussed.
저자 유혜리, 신웅, 박상준, 박정배, 김주현
소속 부경대
키워드 organic solar cells; Low band gap
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