| 학회 |
한국고분자학회 |
| 학술대회 |
2014년 가을 (10/06 ~ 10/08, 제주 ICC) |
| 권호 |
39권 2호 |
| 발표분야 |
분자전자 부문위원회 |
| 제목 |
Nano-Confinement Effect on Conductive Polymers and Its Application to Organic Solar Cells |
| 초록 |
In the present study, we employed scalable nano-imprinting lithography as a method to change the molecular orientation by exploiting nano-confinement and also studied its application to organic solar cells. We fabricated nanorods of conductive polymers with different chemical structure, dimension, and crystallinity based on patterning with AAO templates. GIWAXS measurements showed different chain orientation and crystallinity different from bulk crystallinity. We adopted P3HT nanorods with face-on orientation for the ordered heterojunction organic solar cell architecture. We were able to control both chain orientation and domain size of organic solar cells with patterned nano-imprinted of P3HT nanorods coupled with thermal annealing to control the mutual diffusion between P3HT and PCBM. Finally, we optimized the morphology of ordered organic solar cells and obtained more than 5 times higher power conversion efficiency than bilayer organic solar cells. |
| 저자 |
고종국1, 송지연1, 김태용1, 윤현식2, 이창희1, Ruediger Berger3, 차국헌1
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| 소속 |
1서울대, 2서울과학기술대, 3Max Planck Institute for Polymer Research |
| 키워드 |
conductive polymer; morphology; nanoconfinement; organic solar cell
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| E-Mail |
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