화학공학소재연구정보센터
학회 한국고분자학회
학술대회 2008년 가을 (10/09 ~ 10/10, 일산킨텍스)
권호 33권 2호
발표분야 기능성 고분자
제목 InterlayerLength Effect of Inorganic Fillers on Ion Conducting Behaviors of Polymeric Composite Electrolytes
초록 Solid polymer electrolytes were intended to be applicable to lithium polymer batteries, because of mechanical property, processing flexibility, and safety. However, their conductivity at room temperature is usually too low, so it is needed to overcome this problem. In this work, the composite electrolytes based on poly(ethylene oxide) (PEO) and layered fillers were prepared to study the filler effects on the mechanical strength and electrochemical properties. The effect of layer-structured fillers on the tensile strength for polymer electrolyte film was discussed for analyzing the mechanical properties. As a result, the interlayer length of the layered fillers had been changed, and thus the micro-structures and ion transfer had been modified. Furthermore, the ionic conductivity was enhanced with increasing filler contents because of the decreased crystallinity of the composites.
저자 김 석1, 한아름1, 이재락1, 박수진2
소속 1한국화학(연), 2인하대
키워드 conducting behaviors; composite electrolytes; crystallinity; interlayer spacing
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