| 학회 |
한국공업화학회 |
| 학술대회 |
2017년 봄 (05/10 ~ 05/12, 광주 김대중컨벤센센터(Kimdaejung Convention Center)) |
| 권호 |
21권 1호 |
| 발표분야 |
디스플레이 |
| 제목 |
The self-assembly behaviors of norbornene-based polymers depending on side-chains |
| 초록 |
A series of polynorbornenes (A3PN and BP3PN) is newly designed and synthesized to understand dendronized side-chains effect on the self-assembly structures. A3PN and BP3PN were synthesized via ring-opening metathesis polymerization (ROMP) with high molecular weights and narrow polydispersity indices. From the diffraction results combined with thermal and microscopic ones, we could identify the phase transitions and molecular packing structures of A3PN and BP3PN. A3PN with simple alkyl chain dendrons forms the columnar nematic liquid crystal phase. BP3PN with biphenyl mesogen and triethylene oxide linker between the alkyl chain and the polynorbornene main chain forms smectic A liquid crystal phase. It is realized that the different chemical structure and physical interaction of side chains result in the different self-assembly structures between A3PN and BP3PN. This work was supported by BK21 Plus program, the BRL 2015042417, Mid-Career Researcher Program (2016R1A2B2011041). |
| 저자 |
구자현, 정광운
|
| 소속 |
전북대 |
| 키워드 |
self-assembly; liquid crystal
|
| E-Mail |
|
