화학공학소재연구정보센터
학회 한국화학공학회
학술대회 2011년 봄 (04/27 ~ 04/29, 창원컨벤션센터)
권호 17권 1호, p.486
발표분야 에너지
제목 Electrochemical Reduction of Uranium from Porous 17 kg-Uranium Oxide Pellets by Selection of Optimal Cathode/Anode Surface Area Ratio
초록 An electrochemical reduction of metal oxide forms to their metallic forms has been evaluated as a simple, cost-effective and environmentally friendly process for the production of various metals. In this study, influence of cathode/anode surface area ratio on electrochemical reduction behavior of uranium oxide in a molten LiCl-Li2O electrolyte was investigated. In a bench-scale test, cathode/anode surface area ratio in the vicinity of 2.6 was shown to the most efficient to achieve high current density and to produce metallic uranium from uranium oxide when mass of LiCl-Li2O electrolyte in an electrolysis cell is large enough. We set up a 17 kg-uranium oxide electrolysis cell to have the cathode/anode surface area ratio of 2.6 and successfully performed electrochemical reduction of uranium oxide to metallic uranium.
저자 최은영1, 정상문2, 허진목1, 최인규1, 권선길1, 강대승1, 홍순석1, 신호섭1, 유민아1
소속 1한국원자력(연), 2충북대
키워드 electrochemical reduction; uranium; uranium oxide; pyroprocess
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