화학공학소재연구정보센터
학회 한국고분자학회
학술대회 2011년 가을 (10/06 ~ 10/07, 김대중 컨벤션센터)
권호 36권 2호
발표분야 고분자합성-구조제어중합
제목 Synthesis and Characterization of Poly[ether-b-(urea-amide)] Containing Polyamide12(PA12) Segments
초록 Poly(γ-BLG)-(PA12)-Poly(γ-BLG), a A-B-A type triblock copolymer was synthesized by reaction between γ-benzyl-L-glutamate-NCA(γ-BLG) and NH2 end-capped polyamide12(PA12) oligomer. The chemical structure of the triblock copolymer was identified by using FT-IR and 1H-NMR. Poly[ether-b-(urea-amide)] block copolymer was obtained with the triblock copolymer and NCO-terminated polyether prepared by reaction isophorone diisocyanate(IPDI) to poly(tetramethylene glycol)(PTMG). The final block copolymers have relatively low melting point and high modulus, and showed typical properties of thermoplastic elastomers.
저자 김두현, 이지훈, 김형중
소속 공주대
키워드 polyamide; oligomer; elastomer
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