| 초록 |
Ethylene oxide (EO) unit of the Triton X family is critical for the surfactant-assisted polymerization of the ionic liquid-based polymer electrolytes film at the plasma-liquid interface. This unit employed as an assisted-cross linking agent for the liquid plasma polymerization while ionic liquids are used as building blocks. The relationship between number of the EO unit and thickness and ionic conductivity of the ionic-based polymer electrolyte film was examined. Three different types of the Triton X were used as Triton X100, Triton X405 and Triton X705 with the number of EO unit of 9, 35 and 55, respectively. The thickness of the films increased from 1.94 µm to 8.24 µm at the same Triton X molar content of 6% in liquid mixture when the number of the EO unit increased from 9 to 55, respectively. The ionic conductivity of the obtaine polymer electrolytes increased with increasing of the number of the EO unit. This unit plays a decisive role in the growth in thickness and the increase in ionic conductivity of the polymer electrolyes. |
