초록 |
Prussian blue analogs or double metal cyanide (DMC) complexes are well-known solid compound because of their diverse applications in both academy and industry. In this study, we have investigated DMC compounds as heterogeneous catalysts for various organic reactions such as ring-opening polymerization and hydroaddition reactions. The chemical structures and crystal architectures of the solid catalysts were investigated by commonly used techniques such as Fourier transform infrared, NMR, X-ray photoelectron spectra, inductively couple plasma–optical emission spectroscopy, and powder X-ray diffraction. The resultant DMC catalysts exhibited good to excellent performance for the ring-opening polymerization and hydroaddition reactions, produced products with high yields and high selectivities. |