| 학회 |
한국화학공학회 |
| 학술대회 |
2008년 봄 (04/23 ~ 04/25, 제주ICC) |
| 권호 |
14권 1호, p.1372 |
| 발표분야 |
촉매 및 반응공학 |
| 제목 |
Kinetic resolution of terminal epoxides with phenols catalyzed by (salen) Co-BF3 immobilized on meso/ micro porous silicates |
| 초록 |
A route to synthesize porous materials with a meso/ microscopic pore system has been investigated in this work. These meso/ micro porous structured silicates have been applied as a support in the kinetic resolution of epichlorohydrine with phenol to synthesize optically pure α-arloxy alcohols. The catalyst has been prepared by immobilization of (Salen) Co-BF3 on MCM-41, MCM-48, and on the surface of SiO2. The immobilized salen catalysts showed a high enantioselectivity in the kinetic resolution. |
| 저자 |
카테라 라울, 김용석, 곽소봉, 김건중
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| 소속 |
인하대 |
| 키워드 |
Immobilization; Kinetic resolution; cobalt salen; MCM-41; MCM-48
|
| E-Mail |
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| 원문파일 |
초록 보기 |
