화학공학소재연구정보센터
학회 한국고분자학회
학술대회 2019년 봄 (04/10 ~ 04/12, 부산컨벤션센터(BEXCO))
권호 44권 1호
발표분야 콜로이드 및 분자조립 부문위원회
제목 Dynamics of polymer thin films on different interface interaction
초록 Polymer mobility of confined system has been studied by dewetting and diffusion dynamics measurements. Especially, the polymer mobility is greatly influenced by adjecent polymer layer. In this study, we mainly focused on the polymer-polymer interaction. First, the effect of attractive on the dewetting phenomenon was investigated by using graphene oxide (GO) sheets. when wrinkled GO was placed at the interface between poly(methyl methacrylate) (PMMA) and Si substrates, the dewetting behavior were inhibited due to the amphiphilic properties of GO. In the case of diffusion dynamics, we used repulsive wall (Polystyrene, PS) samples as a model composite system of diffusion. Polymer mobility of confined systems was measured by a neutron reflectivity technique. The diffusion dynamics was signitantly affected by neighboring surfaces which have eighter attractive or repulsive interaction with polymers.
저자 조경일1, 최기인1, 김태호2, 구자승3
소속 1한국원자력(연), 2한국기술교육대, 3충남대
키워드 polymer; dynamics; interface interaction; dewetting; diffusion
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