화학공학소재연구정보센터
학회 한국화학공학회
학술대회 2004년 가을 (10/29 ~ 10/30, 호서대학교(아산캠퍼스))
권호 10권 2호, p.1349
발표분야 분리기술
제목 Performance of facilitated transport membranes containing SPEEK-AgNO3  for isoprene/n-pentane separation
초록 The facilitated transport membranes with sulfonated poly(ether ether)ketone (SPEEK)-AgNO3 is based on complexes between silver ions and olefin, these membranes were prepared and tested for separation of olefin/paraffin. The facilitated transport membranes showed high selectivity of isoprene over n-pentane and long-term stability. Depending on various reaction conditions, the degree of sulfonation (DS) of SPEEK was measured by 1H NMR spectroscopy.  In the membranes containing SPEEK-AgNO3, the performance of the membranes was affected by the DS of SPEEK. As the DS of SPEEK was increased, the selectivity of isoprene over n-pentane was increased and the stability of that was continued.
저자 최현우1, 최대기1, 김훈식1, 김동범2, 이창하3
소속 1한국과학기술(연), 2세종대, 3연세대
키워드 Isoprene/n-pentane separation; Sulfonated poly(ether ether)ketone (SPEEK); Facilitated transport membrane; π-complex
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