| 학회 |
한국고분자학회 |
| 학술대회 |
2009년 봄 (04/09 ~ 04/10, 대전컨벤션센터) |
| 권호 |
34권 1호 |
| 발표분야 |
고분자 구조 및 물성 |
| 제목 |
A Study of Spin-Coated Films of Poly(3-hydroxybutyrate-co-3-hydrohexanoate) by 2D Correlation Spectroscopy and 2D Gradient Mapping Technique |
| 초록 |
Poly(3-hydroxybutyrate) (PHB) has been studied extensively as an environment-friendly polymers. PHB-based copolymers, such as poly(3-hydroxybutyrate-co-3-hydrohexanoate) (P(HB-co-HHX)), has recently been introduced. In this presentation, principal component analysis-based two-dimensional (PCA2D) correlation spectroscopy was applied to the temperature-dependent infrared-reflection absorption (IRRAS) spectra of a spin-coated film of P(HB-co-HHx) copolymer. The potential of a two-dimensional (2D) gradient mapping technique that utilized the eigenvalue manipulating transformation (EMT) of the spectral data set will be also introduced. The EMT technique, by lowering the power of a set of eigenvalues associated with the original data, enhances the contributions of minor principle components (PCs). This improvement for 2D mapping is potentially very important to determine the transition temperatures, which are not readily detected in convention spectral analysis. |
| 저자 |
박연주1, 유수련1, 김승빈2, Isao Noda3, 정영미1
|
| 소속 |
1강원대, 2포항공과대, 3Procter & Gamble Company |
| 키워드 |
PHB; 2D gradient mapping; 2D correlation spectroscopy
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| E-Mail |
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