화학공학소재연구정보센터
학회 한국화학공학회
학술대회 2012년 봄 (04/25 ~ 04/27, 제주 ICC)
권호 18권 1호, p.73
발표분야 고분자
제목 Efficient polymer light-emitting diodes and polymer solar cell with polyfluorene derivatives as an electron injecting layer and as a buffer layer
초록 Many types of conjugated polymers have been reported, in attempts to enhance efficiency for polymer solar cells (PSCs) and polymer light-emitting diodes (PLEDs). In particular, water-soluble conjugated polymers have also been extensively investigated due to multilayer formation capability. Recently, we synthesized a noble alcohol-soluble polyfluorene derivative (PF-GOH) containing four hydroxyl groups in each repeat unit in a multi-step procedure. The PF-GOH poly[9,9-bis(2-(2-(2-(2,3-dihy-droxy)-methoxyethoxy)ethoxy)ethoxy)ethyl)-fluorene-2,4-diyl]was characterized by UV-visible and photoluminescence spectroscopy, gel permeation chromatography and cyclovoltametry, etc. It was able to apply in polymer solar cell and polymer light-emitting diode as buffer layer and electron injecting layer, respectively. To investigate the electron injection properties of PF-GOH, PLEDs with an ITO/PEDOT:PSS/MEH-PPV/PF-GOH/Al configuration were fabricated. Polymer solar cell were fabricated with ITO/PEDOT:PSS/P3HT:PCBM/PF-GOH/Al configuration. The experimental results will be presented in detail.
저자 박영민1, 권재택1, 김일구1, 최철호1, 강혜정1, 이상희2, 신진국1, 이수형3, 이연식3
소속 1전자부품(연), 2군산대, 3전북대
키워드 buffer layer; polymer solar cell; polymer LED
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