화학공학소재연구정보센터
학회 한국공업화학회
학술대회 2022년 봄 (05/11 ~ 05/13, 제주국제컨벤션센터(ICC JEJU))
권호 26권 1호
발표분야 포스터-석유화학·재생연료
제목 Facile synthesis of iron-based catalysts for the direct CO2 conversion to liquid hydrocarbons
초록 The progress in the field of CO2 hydrogenation to highly valuable chemicals have received considerable attention over iron-based catalysts. In this work, iron-metal oxides (FeMOx) were synthesized, characterized, and examined to produce liquid hydrocarbons (C5+) from CO2 hydrogenation. The iron oxide shows 4.8% CO2 conversion and 0.7% C5+ yield using H2/CO2 ratio of 3:1 at space velocity of 4000 mLg-1h-1. On the other hand, with the iron-metal oxides (FeMOx) catalysts CO2 conversion drastically increases to 34.6% and C5+ yield increases to 14.3%. The considerable increase in the CO2 conversion and hydrocarbon selectivity, with the addition of metal in iron-based catalysts also enhances the Hägg iron carbide (χ-Fe5C2) phase which facilities the chain-growth reactions.
저자 Sheraz Ahmed, Muhammad Kashif Khan, 김재훈
소속 Sungkyunkwan Univ.
키워드 CO2 hydrogenation; Iron-metal oxides; liquid hydrocarbons
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