| 학회 |
한국고분자학회 |
| 학술대회 |
2011년 봄 (04/07 ~ 04/08, 대전컨벤션센터) |
| 권호 |
36권 1호 |
| 발표분야 |
고분자 구조 및 물성 |
| 제목 |
FT-IR study on the stabilization reactions of poly(acrylonitrile-co-itaconic acid) for carbon fiber |
| 초록 |
During thermo-oxidative stabilization, polyacrylonitrile (PAN) is converted into infusible and nonflammable fibers for further carbonization. The structure changes during stabilization depend on the composition of precursor. Generally, PAN precursor is incorporated with Itaconic acid (IA) comonomer because carboxylic acid groups can initiate cyclization reactions at low temperature. In addition, IA contains two carboxylic groups which provide more opportunities for interaction between carboxylic group and nitrile group. However, previous results suggested that the function of carboxylic acid unit is more complex than merely initiating the reaction. In this study, further study on the evolution of PAN structure was proceeded by tracing the changes of functional groups by using Fourier transform infrared (FT-IR) spectroscopy. The effect of IA content and IA distribution was also studied. Acknowledgement: This work was supported by a grant from KIST institutional program. |
| 저자 |
윤테우엔1, 구본철2, 박민3, 김준경3, 홍성철1
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| 소속 |
1세종대, 2KIST 전북, 3KIST |
| 키워드 |
FTIR; stabilization
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| E-Mail |
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