화학공학소재연구정보센터
학회 한국공업화학회
학술대회 2022년 봄 (05/11 ~ 05/13, 제주국제컨벤션센터(ICC JEJU))
권호 26권 1호
발표분야 포스터-환경·에너지
제목 Oligo(ethylene glycol)-Based Electron Transport Layers for Reproducible Fabrication of High-Performance and Stable Organic Solar Cells
초록 Two naphthalene diimide (NDI)-based polymers, P(NDIDEG-T) and P(NDITEG-T), with different lengths of oligoethylene glycol (OEG) side chains are used as electron transporting layers (ETLs). By depositing the ETLs on PM6:Y6 with eco-friendly water/ethanol co-solvents, a power conversion efficiency (PCE) of 15.43% is achieved, which is substantially higher than that of an OSC without an ETL (9.93%) and comparable to that of an OSC with a representative PFN-Br ETL (15.34%). The P(NDIDEG-T)–based OSCs show both enhanced PCEs and better reproducibility than their P(NDITEG-T)–based counterparts, which are attributed to the lower surface tension and improved film uniformity of the P(NDIDEG-T) ETL. Also, the P(NDIDEG-T) ETL realizes OSCs with higher storage stability and more thickness-tolerant performance than the P(NDITEG-T) and PFN-Br ETLs. Our study provides useful guidelines for the design of ETLs suitable for the fabrication of high-performance, reproducible, and stable OSCs.​​
저자 임철희, 이승진, 김영웅, 김동욱, 정다현, 김건우, 김진석, 김범준
소속 한국과학기술원
키워드 Organic solar cells; Electron transporting layer; Reproducibility; Stability
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