학회 |
한국고분자학회 |
학술대회 |
2015년 가을 (10/06 ~ 10/08, 대구컨벤션센터(EXCO)) |
권호 |
40권 2호 |
발표분야 |
분자전자 부문위원회 II |
제목 |
Highly Stable Polymer Solar Cells Based on Poly(dithienobenzodithiophene-co-thienothiophene) |
초록 |
It is important to develop new donor (D)−acceptor (A) type low band gap polymers for highly stable polymer solar cells (PSCs). The polymers consist of dithienobenzodithiophene (DTBDT) moieties with expanded conjugation side groups as donors and 2-ethyl-1-(thieno[3,4-b]thiophen-2-yl)hexan-1-one (TTEH) or 6-octyl-5H-thieno[3′,4′:4,5]thieno[2,3-c]pyrrole- 5,7(6H)-dione (DTPD) as acceptors to give pDTBDT-TTEH and pDTBDT-DTPD polymers, respectively. The pDTBDT-TTEH is quite flat, resulting in a highly crystalline film.Here, we describe the synthesis and photovoltaic properties of two D−A type low band gap polymers. Photovoltaic devices based on pDTBDT-TTEH and pDTBDT-DTPD exhibited power conversion efficiencies (PCEs) of 6.74% and 4.44%, respectively. |
저자 |
김윤희1, 김봉수2, 주상용3, 손해정2, 김형남1, 조철성1, 윤영운2, 신나라2, 윤희준1
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소속 |
1경상대, 2KIST, 3연세대 |
키워드 |
OPV; DTBDT; Solar Cell; PSCs
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E-Mail |
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