| 학회 |
한국고분자학회 |
| 학술대회 |
2020년 가을 (10/05 ~ 10/08, 부산컨벤션센터(BEXCO)) |
| 권호 |
45권 1호 |
| 발표분야 |
기능성 고분자 |
| 제목 |
Fabrication of Polymer Particles with Controllable and Sophisticated Structures for High Immobilization of Noble-metal Nanoparticles |
| 초록 |
This research introduces the fabrication of cationic polymer particles with controllable and sophisticated structures for the high immobilization of noble-metal nanoparticles(NPs). The manipulation includes the use of a cationic extra monomer to synthesize solid spheres polystyrene(PS) with cationic character, followed by their transformation into complex-structured particles via the phase separation route in a seeded dispersion polymerization. Control of the phase separation enable us to obtain PS particles with cage-and bowl-like shapes as well as hollow structures. The large surface areas of the complex-structured particles, as theoretically calculated using simple models, and the electrostatic attraction between them and the negatively charged noble-metal NPs, as experimentally observed, enable the high immobilization of noble-metal NPs onto their surfaces. |
| 저자 |
김혜지1, 현동춘1, 안형주2, 문건대3, 박주향1, 서호준1, 김다인1, 홍상기1
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| 소속 |
1경북대, 2포항가속기(연), 3한국생산기술(연) |
| 키워드 |
fabrication of polymer particle; sophisticated-structured colloid; phase separation; noble-metal nanoparticle
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| E-Mail |
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