| 학회 |
한국화학공학회 |
| 학술대회 |
2022년 봄 (04/20 ~ 04/23, 제주국제컨벤션센터) |
| 권호 |
28권 1호, p.1008 |
| 발표분야 |
[주제 12] 화학공학일반(부문위원회 발표) |
| 제목 |
Microwave-assisted phenolation of acid-insoluble Klason lignin and its application in adhesion |
| 초록 |
Lignin, a by-product from forest waste and agriculture, is a promising alternative for fossil-derived materials. However, due to the high crosslinking between aromatic units in lignin structure, it needs to be modified before applicable for further usage. In this research, microwave system was employed for acid-insoluble phenolation. By using microwave irradiation, phenolation process can occur at minder condition (100 o C for 0 min) compared with conventional heating (180 oC for 6h). NMR, TGA, and DSC were used for lignin characterization and DFT was carried out to investigate the effect of microwave during the reaction. The solubility of modified lignin in organic solvents, such as tetrahydrofuran and methanol, is highly enhanced, which allows using lignin as adhesive on glass, polyethylene naphtalate, and polyimide. |
| 저자 |
Tran Tuan Ngoc1, 고영표1, 김성수2, 문장혁2, 최재욱1, 김광호1, 김창수1, 하정명1, 김희숙1, 정근홍3, 유천재1, 이현주1
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| 소속 |
1한국과학기술(연), 2중앙대, 3육군사관학교 화학과 |
| 키워드 |
에너지 환경(Energy and Environment) |
| E-Mail |
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| 원문파일 |
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