| 학회 |
한국화학공학회 |
| 학술대회 |
2016년 봄 (04/27 ~ 04/29, 부산 BEXCO) |
| 권호 |
22권 1호, p.997 |
| 발표분야 |
재료 |
| 제목 |
Conformal coating of polyaniline on the modified silicon nanoparticles embedded in conductive nanocellulose |
| 초록 |
Here we describe a unique conductive bacterial cellulose (BC) composite with silicon nanoparticles (SiNPs) and polyaniline. BC was used as a template for binding SiNPs resulting in a very promising anode material for Li-ion rechargeable batteries that showed a high specific capacity. The surfaces of the SiNPs were modified with phytic acid to enhance the binding of aniline monomer to the surface. A conformal coating of polyaniline (PANi) was formed on the modified SiNPs by in-situ polymerization of aniline monomers. We also found that the phytic acid on the SiNPs was critical to ensure encapsulation of SiNPs with PANi. In addition, the phosphoric acid-tagged surface of the SiNPs enhanced the adhesion of SiNPs to the BC fibers. The resulting three dimensional network of BC was flexible and provided stress dissipation in the conductive BC composites. Flexural testing of conductive BC composites showed stable electrical conductivity even after repetitive bending over 100 times. |
| 저자 |
박민성, 신성철, 정은수, 신동혁, 현진호
|
| 소속 |
서울대 |
| 키워드 |
화공나노소재; 화공바이오소재
|
| E-Mail |
|
| 원문파일 |
초록 보기 |
