| 학회 |
한국고분자학회 |
| 학술대회 |
2006년 봄 (04/06 ~ 04/07, 일산킨텍스) |
| 권호 |
31권 1호 |
| 발표분야 |
고분자 합성 |
| 제목 |
MALDI-TOF analysis of functionalized poly(ethylene oxide). |
| 초록 |
n-Butyllithium-initiated ring-opening polymerization of ethylene oxide in the presence of t-BuO-K+ was successfully carried out in the mixture of benzene and dimethylsulfoxide at 40℃ for 48 h. This polymerization was found to proceed with a living manner resulting in the production of the living alkali metal polymeric alkoxide. Thus, the chain-end functionalization of the resulting polymer can be achieved quantitatively. The matrix-assisted laser desorption ionization-time of flight mass spectrometry (MALDI-TOF MS) analysis for the resulting polymers was carried out. The spectra inform us that the resulting polymeric alkoxide seems to retain three different types of the growing chain-ends. In this presentation, we will report the result for characterization of the PEO-based materials via MALDI-TOF analysis. |
| 저자 |
이철한1, 박형수1, 김정안2, 황승상3, 홍순만3, 곽순종3, 박흥목1, 최송이2, 김경민2, 김지희4
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| 소속 |
1서강대, 2경희대, 3한국과학기술(연), 4율촌화학 |
| 키워드 |
PEO |
| E-Mail |
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