| 학회 |
한국고분자학회 |
| 학술대회 |
2013년 봄 (04/11 ~ 04/12, 대전컨벤션센터) |
| 권호 |
38권 1호 |
| 발표분야 |
고분자구조 및 물성 |
| 제목 |
Reversible transformation of peptide-mimic poly(n-hexyl isocyanate) in thin films via selective solvent-annealing |
| 초록 |
For the first time, We demonstrate the conformational and structural details of peptide-mimic poly(n-hexyl isocyanate) (PHIC), which have received considerable attention because of their unique characteristics, structural feature and potential applications in various fields. A well-ordered hexagonal close packing (HCP) structure of PHIC with 83 helical conformation was unequivocally observed in the nanoscale thin films that were selectively annealed with carbon disulfide (CS2). In another case, a well-ordered multi-bilayer structure of the polymer with β-sheet conformation was also unequivocally formed in the films that were selectively annealed with toluene. In addition, reversible transformation between these two self-assembled structures was demonstrated by consecutive annealings with CS2 and toluene. |
| 저자 |
위동우1, 노예철1, 민준근2, 윤진환3, 안병철1, 정정운1, 정성민1, 김경태1, 김영용1, 김종현1, 김창섭1, 이재석2, 이문호1
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| 소속 |
1포항공과대, 2광주과학기술원, 3동아대 |
| 키워드 |
conformation change; hexagonal close packing structure; multi-bilayer structure; peptide-mimic poly(n-alkyl isocyanate); reversible order–order transition; selective solvent annealing; self-assembly
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| E-Mail |
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