| 학회 |
한국고분자학회 |
| 학술대회 |
2022년 봄 (04/06 ~ 04/08, 대전컨벤션센터) |
| 권호 |
47권 1호 |
| 발표분야 |
분자전자 부문위원회 |
| 제목 |
The effect of doping and thermoelectric properties of the extended planar backbone of donor-acceptor polymers |
| 초록 |
Designing of the polymer backbone provides a new avenue for improving charge transport and doping efficiency; Herein, a new donor-acceptor conjugated polymer with the extended planar backbone, C6-ICPDPP, is synthesized for the investigation between the backbone construction and thermoelectric behavior. The expended planar backbone of C6-ICPDPP consists of a combination of fused heterocyclic donor compounds, exhibiting p-type characteristics. Due to the investigation of the backbone structures, two types of solvents with different boiling points are prepared to make different structural behaviors of the C6-ICPDPP, however, their thermoelectric behaviors with doping are similar. Meanwhile, the type of charge carriers of C6-ICPDPP changes from positive to negative at high doping concentrations, and both power factors are 1.32 mK2 (p-type) and 0.410 µW/mK2 (n-type), respectively. This work would provide strategies for the polymer backbone engineering and electrical behaviors with doping. |
| 저자 |
이택성1, 이수빈2, 최도영2, 서의현1, 안태규3, 정용진3, 김윤희2, 장재영1
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| 소속 |
1한양대, 2경상대, 3한국교통대 |
| 키워드 |
organic thermoelectrics; donor-acceptor conjugated polymer; diketopyrrolopyrrole; extended planar backbone; polarity change of majority carriers
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| E-Mail |
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