| 학회 |
한국화학공학회 |
| 학술대회 |
2022년 봄 (04/20 ~ 04/23, 제주국제컨벤션센터) |
| 권호 |
28권 1호, p.1092 |
| 발표분야 |
[주제 12] 화학공학일반(부문위원회 발표) |
| 제목 |
Intrinsically stretchable benzotriazole-based polymer semiconductors for stretchable electronics |
| 초록 |
Despite emerging scientific interest in polymer-based stretchable electronics, the trade-off between crystallinity and ductility of semiconducting polymers hinders the development of high-performance stretchable electronics. Here, we report a simultaneous enhancement of crystallinity and ductility of a benzotriazole-based polymer thin film enabled by reversible orientation of bimodal crystallites. The thin film shows bimodal crystalline structure with enhanced degree of crystallinity upon thermal annealing, and the annealed thin film yields improved charge carrier mobility (μ) of 0.2 cm2/V-s and crack onset strain (εc) of 100%, which are two orders of magnitude and two times higher than those of the as-prepared thin film (μ = 0.002 cm2/V-s; εc < 50%), respectively. Our results provide new insight into how crystalline structure affect μ and ductility of semiconducting polymer thin films and will facilitate the design of high-performance and stretchable semiconducting polymers. |
| 저자 |
김예진1, 안형주2, 성민기3, 유현진1, 변희경1, 이정훈3, 박가연1, 이병훈1
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| 소속 |
1이화여자대, 2포항가속기(연), 3동서대 |
| 키워드 |
고분자(Polymer) |
| E-Mail |
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| 원문파일 |
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