| 학회 | 한국공업화학회 |
| 학술대회 | 2018년 가을 (10/31 ~ 11/02, 제주국제컨벤션센터(ICC JEJU)) |
| 권호 | 22권 2호 |
| 발표분야 | 정밀화학_포스터 |
| 제목 | Optimization study for the one-step synthesis of laurolactam as a monomer for PA-12 |
| 초록 | Polyamide-12 (PA-12) is one of the recently developed nylon polymers. PA-12 is also used as a hard segment in PA-12 elastomers, an important subgroup of polyamide based thermoplastic elastomers (TPAEs). Due to its excellent chemical and mechanical properties like tensile strength, hardness, abrasion resistance, water and chemical resistance, the demand for PA-12 in the global market will continue. Laurolactam, the target material of this study, is a monomer of PA-12 and PA-12 is produced through its ring opening polymerization. In this study, we have developed an efficient one-step process for the synthesis of laurolactam from a commercially available cyclododecanone via a Beckmann rearrangement reaction. In addition, we have developed an efficient purification method and studied the optimization of the reaction scale for industrial applications. |
| 저자 | 김남태, 양해민, 김주희, 박종범, 원영대, 문소정, 김영규 |
| 소속 | 서울대 |
| 키워드 | laurolactam; monomer; polyamide-12; thermoplastic elastomer |
