화학공학소재연구정보센터
학회 한국고분자학회
학술대회 2008년 가을 (10/09 ~ 10/10, 일산킨텍스)
권호 33권 2호
발표분야 고분자 합성
제목 Water-like behavior of ionic liquids in composite membranes for high temperature polymer electrolyte fuel cells
초록 Composite membranes consisting of room temperature ionic liquid (IL) and sulfonated polymer were prepared and characterized for their application to the anhydrous high temperature PEFCs. The ionic conductivity of several IL and their composite membranes were investigated to study the behavior of IL in the composite membranes. The ionic conductivity increases with elevating temperature. The various contents of IL in composite membrane were employed, and the proton conductivity was found to increase with increasing IL contents. Degree of sulfonation of sulfonated polymer also effect on the ionic conductivity. In addition, the performance of composite membrane under anhydrous system was depending on that of polymer matrix under fully hydrated condition. As a result, these IL in composite membranes behave like water in water swelled polymer. These IL-based membranes are proposed as new polymer electrolytes for high temperature PEFCs.
저자 조은경1, 박진수2, 양태현2, 임성대2, 이원용2, 김창수2, 박승빈3
소속 1한국과학기술원(kaist) / 한국에너지기술(연), 2한국에너지기술(연), 3한국과학기술원(kaist)
키워드 composite membrane; ionic liquid; high temperaturePEFC
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