화학공학소재연구정보센터
학회 한국화학공학회
학술대회 2009년 봄 (04/23 ~ 04/24, 광주 김대중컨벤션센터)
권호 15권 1호, p.492
발표분야 에너지
제목 Preparation of Ionic Liquid Based Membranes in the Presence of Acid for Anhydrous and High Temperature Fuel Cells
초록 Composite electrolyte membranes embedding ionic liquid in hydrocarbon polymers were prepared for anhydrous and high temperature polymer electrolyte fuel cells (HT-PEFCs). Proton can be transported through the membranes at a high temperature and anhydrous condition because ionic liquids behaved like water in the composite membrane. Ionic liquids have low ionic conductivity in the composite membranes due to high viscosity and low mobility. To increase the ionic conductivity, the acid containing common anion of the ionic liquid was added to the membranes with low content. The electrochemical properties of composite membranes were investigated using thermogravimetric analyzer (TGA), differential scanning calorimetry (DSC) and impedance spectroscopy under anhydrous condition. Consequently the composite membranes containing the common anion showed higher ionic conductivity than those containing no common anion. Thus, the ionic conductivity increased with ascending the content of acid.
저자 백지숙1, 박진수2, 양태현2, 박구곤2, 이원용2, 김창수2, 설용건1
소속 1연세대, 2한국에너지기술(연)
키워드 이온성액체; 고분자연료전지; 고온; 탄화수소계 고분자; 복합막
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