화학공학소재연구정보센터
학회 한국공업화학회
학술대회 2017년 봄 (05/10 ~ 05/12, 광주 김대중컨벤센센터(Kimdaejung Convention Center))
권호 21권 1호
발표분야 환경에너지
제목 Effects of Fe:Co ratio of Fe-Co bimetal catalysts for production of  high-calorie synthetic natural gas(SNG) in syngas methanation
초록  Synthetic natural gas has been suggested as a solution for the problem of low-calorie natural gas. In this study, Fe-Co bimetal catalysts with different Fe:Co  ratios were synthesized by the co-precipitation to obtain high-calrorific SNG. The Fe-Co-Al catalysts with various Fe:Co ratios were tested in a fixed bed reactor with flowing syngas with a H2/CO=3. 
 The CO conversion increased with increasing amount of Co in the catalyst. In addition, the activity of water-gas shift (WGS) decreased with the incorporation of Co contents, leading to low CO2 production. At higher Fe/Co ratio (≥2), the preferentially increased hydrocarbon components were light hydrocarbon such as C2-C4 and light paraffin during syngas methanation. Overall, addition of low contents of Co was effective to improve the SNG yield and high calorific SNG.
저자 이지용1, 강석창2, 김형식3, 박진모3, 전기원2
소속 1UST-Krict school, 2한국화학(연), 3한국가스공사
키워드 ron catalyst; cobalt; SNG synthesis
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