| 학회 |
한국공업화학회 |
| 학술대회 |
2021년 봄 (05/12 ~ 05/14, 부산 벡스코(BEXCO)) |
| 권호 |
25권 1호 |
| 발표분야 |
[고분자] 자가치유 및 생체/자연모사 첨단 고분자 소재 |
| 제목 |
Self-Healable Dual Dynamic Supramolecular Network with Quadruple Hydrogen Bonding |
| 초록 |
Self-healing supramolecular network is one of the representative biomimetic intelligent materials that can repair its own structures and functions from the damage by the external environment. Despite their excellent self-healing capabilities, the poor mechanical strengths of self-healing supramolecular networks have limited their widespread industrial applications. In this study, we present a self-healable supramolecular network with enhanced healing capability and mechanical properties through the formation of a dual dynamic network structure composed of quadruple hydrogen bonds and crystalline physical bonds using UPy-end-functionalized semi-crystalline star-shaped supramolecular polymers. The control of crosslinking density for the network was critical to achieving the mechanically robust semi-crystalline supramolecular network with highly efficient healing capability due to their arm-length-dependent phase transformation and dual dynamic healing behavior. |
| 저자 |
정재우 |
| 소속 |
숭실대 |
| 키워드 |
자가치유; 초분자; 네트워크; 수소결합
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| E-Mail |
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