화학공학소재연구정보센터
학회 한국고분자학회
학술대회 2017년 가을 (10/11 ~ 10/13, 제주컨벤션센터)
권호 42권 2호
발표분야 분자전자 부문위원회 I
제목 Structure-Property Relationships of Semiconducting Polymers for Flexible and Durable Polymer Field-Effect Transistors
초록 We report high-performance top-gate bottom-contact flexible field-effect polymer transistors (FETs) fabricated by flow-coating diketopyrrolopyrrole based and naphthalene diimide based polymers as semiconducting channel materials. All of the polymers displayed good FET characteristics with on/off current ratios exceeding 107. The highest hole mobility of 1.51 cm2V-1s-1 and the electron mobility of 0.85 cm2V-1s-1 were obtained from the P(DPP2DT-T2) and P(NDI2OD-Se2) polymer FETs, respectively. The impacts of the polymer structures on the FET performance are well explained by the crystallinity, the tendency of the polymer backbone to adopt an edge-on orientation, and the interconnectivity of polymer fibrils in the film state. Additionally, we demonstrated that all of the polymer-based flexible FETs were highly resistant to tensile stress, with negligible changes in their characteristics during a bending test.
저자 김민제1, 정아라2, 이명재3, 김동진4, 노수희2, 진선미5, Nguyen Dinh Hieu6, 양지혜7, 이경구6, 이은지5, 강문성7, 김현정4, 최종호3, 김봉수2, 조정호1
소속 1성균관대, 2이화여자대, 3고려대, 4서강대, 5충남대, 6군산대, 7숭실대
키워드 Flexible field effect transistors; Structure-property relationship; Organic semiconductors; Carrier mobility; Mechanical stability
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