| 학회 |
한국고분자학회 |
| 학술대회 |
2017년 가을 (10/11 ~ 10/13, 제주컨벤션센터) |
| 권호 |
42권 2호 |
| 발표분야 |
고분자합성 |
| 제목 |
Ultimate Expansion of Controlled Chain Lengths in Rod-Like Polymers Containing Isotropically Bulky Pendants by Ring-Opening Metathesis Polymerization: Access to Hybrid Photonic Crystals |
| 초록 |
Isotropically bulky pendants in the polymer are desired to effectively generate the rod-like backbone through steric repulsion. However, the synthesis of rod-like polymers containing such pendants narrowly dispersed in ultrahigh chain lengths has never been accessible by the conventional polymerization methods. To overcome this limitation, here, we report the ring-opening metathesis polymerization (ROMP) of norbornenyl monomers containing cubic nanocage. The kinetically optimized ROMP was demonstrated to provide the living natures of polymerization in the greatly expanded degree of polymerizations leading to rod-like polymers with ultrahigh chain lengths. The excellent living ROMP allowed the preparation of hybrid rod-like block copolymers (BCPs) containing isotropically bulky pendants and polymeric grafts. The self-assembly of BCPs led to generation of hybrid photonic crystals with highly ordered lamellar nanostructures. |
| 저자 |
채창근, 유용군, 서호빈, 김명진, 박인규, Mallela Yadagiri L. N. Kishore, 이재석
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| 소속 |
광주과학기술원 신소재공학부 |
| 키워드 |
Rod-like polymers; isotropically bulky pendants; ring-opening metathesis polymerization; hybrid photonic crystals
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| E-Mail |
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