화학공학소재연구정보센터
학회 한국공업화학회
학술대회 2021년 가을 (11/03 ~ 11/05, 대구 엑스코(EXCO))
권호 25권 2호
발표분야 포스터-촉매
제목 Production of bis(2-hydroxyethyl) cyclohexane-1,4-dicarboxylate from bis(2-hydroxyethylene terephthalate) by selectively hydrogenation
초록 Bis(2- hydroxyethylene terephthalate) (BHET) is the monomer of PET, which can be easily obtained from PET glycolysis. Bis(2-hydroxyethyl) cyclohexane-1,4-dicarboxylate (BHCD) can be produced by BHET,  which is an important raw material to produce high-value products, 1,4-Cyclohexanedimethanol (CHDM). Thus, utilization of BHET to convert BHCD with high conversion and awesome yield has became urgent project.  In this research, for improving BHET conversion and BHCD yield, various catalysts were tested and engineering parameters including reaction temperature and operation time were adjusted. It is confirmed through various experiments that BHET can be used to produce BHCD with high conversion and excellent yield, besides, the BHET conversion and BHCD yield variation were obtained by comparing adjustment of engineering parameters before and after. In addition, the influence of the catalyst on the cis/trans structure rate of BHCD was also confirmed.
저자 ZHANG HAOXIANG, 최종인, 홍도영
소속 한국화학(연)
키워드 BHET conversion; BHCD yield; engineering parameter
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